Preparation, characterization and structure of ruthenium phosphine complexes containing non-innocent ligands
| Contribuinte(s) |
UNIVERSIDADE DE SÃO PAULO |
|---|---|
| Data(s) |
01/11/2013
01/11/2013
2012
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| Resumo |
Phosphine ruthenate complexes containing the non-innocent ligands 4-chloro-1,2-phenylenediamine (opda-CI) and 3,3',4,4'-tetraamminebiphenyl (diopda) were synthesized and characterized by means of X-ray diffraction, electrochemistry, P-31{H-1} NMR and electronic spectroscopies. Crystals of cis-[RuCl2 (dppb)(bqdi-CI)] complex were isolated as a mixture of two conformational isomers due to different positions of the chlorine atoms of the o-phenylene ligand in relation to the P1 atom of the phosphine moiety. (C) 2011 Elsevier Ltd. All rights reserved. FAPESP FAPESP CAPES (PROCAD) CAPES/PROCAD CNPq CNPq |
| Identificador |
POLYHEDRON, OXFORD, v. 31, n. 1, supl. 1, Part 6, pp. 104-109, 37987, 2012 0277-5387 http://www.producao.usp.br/handle/BDPI/37417 10.1016/j.poly.2011.09.015 |
| Idioma(s) |
eng |
| Publicador |
PERGAMON-ELSEVIER SCIENCE LTD OXFORD |
| Relação |
POLYHEDRON |
| Direitos |
restrictedAccess Copyright PERGAMON-ELSEVIER SCIENCE LTD |
| Palavras-Chave | #RUTHENIUM #PHOSPHINE COMPLEXES #COORDINATION CHEMISTRY #NON-INNOCENT LIGANDS #O-PHENYLENE #TRANSITION-METAL-COMPLEXES #ELECTRONIC-STRUCTURE #BENZOQUINONE DIIMINE #CRYSTAL-STRUCTURE #BIPYRIDINE #CHEMISTRY #QUINONES #SPECTRA #SERIES #CHEMISTRY, INORGANIC & NUCLEAR #CRYSTALLOGRAPHY |
| Tipo |
article original article publishedVersion |
