Ruthenium(II) complexes with 2-(diphenylphosphinomethyl)aniline
| Contribuinte(s) |
UNIVERSIDADE DE SÃO PAULO |
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| Data(s) |
05/11/2013
05/11/2013
2012
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| Resumo |
2-(Diphenylphosphinomethyl)aniline. H2L1, reacts with [RuCl2(PPh3)(3)] to yield the monomeric complexes [RuCl2(H2L1)(PPh3)(CH3CN)], [RuCl2(H2L1)(2)]and the chloro-bridged dimer [(H2L1)(PPh3)Ru(mu-Cl)(2)Ru(PPh3) (H2L1)] depending on the conditions applied. Exclusively the monochelate [RuCl2 (H2L1)(dmso)(2)] is formed during reactions of H2L1 with [RuCl2(dmso)(4)]. H2L1 acts as a neutral, bidentate ligand in all complexes. The products are studied spectroscopically and by X-ray diffraction. (C) 2012 Elsevier Ltd. All rights reserved. DAAD (Germany) DAAD (Germany) CAPES (Brazil) CAPES (Brazil) |
| Identificador |
POLYHEDRON, OXFORD, v. 34, n. 1, supl. 1, Part 6, pp. 108-113, FEB 28, 2012 0277-5387 http://www.producao.usp.br/handle/BDPI/41443 10.1016/j.poly.2011.12.018 |
| Idioma(s) |
eng |
| Publicador |
PERGAMON-ELSEVIER SCIENCE LTD OXFORD |
| Relação |
POLYHEDRON |
| Direitos |
closedAccess Copyright PERGAMON-ELSEVIER SCIENCE LTD |
| Palavras-Chave | #RUTHENIUM #AMINOPHOSPHINE #STRUCTURE ANALYSIS #ANTICANCER AGENT #PHASE-I #PRECLINICAL DEVELOPMENT #LIGANDS #KP1019 #CATALYSTS #FFC14A #CHEMISTRY, INORGANIC & NUCLEAR #CRYSTALLOGRAPHY |
| Tipo |
article original article publishedVersion |
