Unraveling the Mysterious Role of Palladium in Feigl bis(dimethylglyoximate)nickel(II) Spot Tests by Means of Confocal Raman Microscopy


Autoria(s): Huila, Manuel F. G.; Lukin, Nikolas; Parussulo, André Luís Araújo; Oliveira, Pedro V.; Kyohara, Pedro K.; Araki, Koiti; Toma, Henrique Eisi
Contribuinte(s)

UNIVERSIDADE DE SÃO PAULO

Data(s)

05/11/2013

05/11/2013

2012

Resumo

The add protection effect promoted by traces of PdCl2 in [Ni(dmgH)(2)] spot tests was elucidated from confocal Raman microscopy imaging, which revealed the formation of protecting layers of [Pd(dmgH)(2)] closing the extremities of the [Ni(dmgH)(2)] filaments.

FAPESP

FAPESP

CNPq

CNPq

PETROBRAS

PETROBRAS

Identificador

ANALYTICAL CHEMISTRY, WASHINGTON, v. 84, n. 7, pp. 3067-3069, APR 3, 2012

0003-2700

http://www.producao.usp.br/handle/BDPI/41195

10.1021/ac3003352

http://dx.doi.org/10.1021/ac3003352

Idioma(s)

eng

Publicador

AMER CHEMICAL SOC

WASHINGTON

Relação

ANALYTICAL CHEMISTRY

Direitos

closedAccess

Copyright AMER CHEMICAL SOC

Palavras-Chave #NICKEL #BIS(DIMETHYLGLYOXIMATO)NICKEL(II) #DIMETHYLGLYOXIME #GLYOXIME #SPECTRA #COMPLEX #CHEMISTRY, ANALYTICAL
Tipo

article

original article

publishedVersion