Steam reforming of ethanol for hydrogen production on Co/CeO²-ZRO² catalysts prepared by polymerization method
| Contribuinte(s) |
UNIVERSIDADE DE SÃO PAULO |
|---|---|
| Data(s) |
31/10/2013
31/10/2013
15/02/2012
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| Resumo |
Catalysts containing 10%Co supported on CexZr1-xO2 (0 < x < 1) were applied to ethanol steam reforming reactions. The catalysts were characterized by Raman spectroscopy, XANES-H-2 and DRS-UV-Vis. The catalytic tests were conducted at 673, 773 and 873 K, with molar ratios of H2O:ethanol = 3:1. The ethanol conversion and H-2 selectivity were temperature dependent and the association of CeO2 with ZrO2 in the support led to show a low formation of CO, due to the higher mobility of oxygen. (C) 2012 Elsevier B.V. All rights reserved. CNPq MCT |
| Identificador |
MATERIALS CHEMISTRY AND PHYSICS, LAUSANNE, v. 132, n. 2-3, pp. 1029-1034, FEB 15, 2012 0254-0584 http://www.producao.usp.br/handle/BDPI/37131 10.1016/j.matchemphys.2011.12.058 |
| Idioma(s) |
eng |
| Publicador |
ELSEVIER SCIENCE SA LAUSANNE |
| Relação |
Materials Chemistry and Physics |
| Direitos |
closedAccess Copyright ELSEVIER SCIENCE SA |
| Palavras-Chave | #ETHANOL STEAM REFORMING #HYDROGEN #Co/CeO²-ZRO² CATALYSTS #CoO²/ZrO² SOLID-SOLUTIONS #FISCHER-TROPSCH SYNTHESIS #CARBON-MONOXIDE #COBALT OXIDES #FUEL-CELLS #CO #COMBUSTION #OXIDATION #TEMPERATURE #CE1-XZRXO2 #MATERIALS SCIENCE, MULTIDISCIPLINARY |
| Tipo |
article original article publishedVersion |
