Laser-flash photolysis of alpha-brominated o-xylenes
| Contribuinte(s) |
Universidade Estadual Paulista (UNESP) |
|---|---|
| Data(s) |
18/03/2015
18/03/2015
13/04/2001
|
| Resumo |
The flash photolysis (lambda = 266 nm) of four alpha -brominated omicron -xylenes in apolar solvents gives two transients characterized, depending on parent compound substitution, as either monoradicals or carbenes, and quinodimethanes. alpha -Bromomethylbenzyl radical is characterized and the novel species alpha,alpha'-dibromo-omicron -xylylene and omicron-(alpha,alpha -dibromomethyl)benzyl carbene are described for the first time. (C) 2001 Elsevier Science B.V. All rights reserved. |
| Formato |
1-5 |
| Identificador |
http://dx.doi.org/10.1016/S1010-6030(01)00384-7 Journal Of Photochemistry And Photobiology A-chemistry. Lausanne: Elsevier Science Sa, v. 140, n. 1, p. 1-5, 2001. 1010-6030 http://hdl.handle.net/11449/116809 10.1016/S1010-6030(01)00384-7 WOS:000168005200001 |
| Idioma(s) |
eng |
| Publicador |
Elsevier B.V. |
| Relação |
Journal Of Photochemistry And Photobiology A-chemistry |
| Direitos |
closedAccess |
| Palavras-Chave | #flash-photolysis #quinodimethanes #photohomolysis #monoradicals #carbenes #alpha-brominated o-xylenes |
| Tipo |
info:eu-repo/semantics/article |
