Photoluminescence properties of CaTiO3:Eu3+ nanophosphor obtained by the polymeric precursor method


Autoria(s): Mazzo, Tatiana Martelli; Rocha Oliveira, Lucas Mendonca da; Macario, Leilane Roberta; Avansi, Waldir; Andre, Rafaela da Silveira; Viana Rosa, Ieda Lucia; Varela, José Arana; Longo, Elson
Contribuinte(s)

Universidade Estadual Paulista (UNESP)

Data(s)

03/12/2014

03/12/2014

15/05/2014

Resumo

Coordenação de Aperfeiçoamento de Pessoal de Nível Superior (CAPES)

Fundação de Amparo à Pesquisa do Estado de São Paulo (FAPESP)

Conselho Nacional de Desenvolvimento Científico e Tecnológico (CNPq)

Processo FAPESP: 98/14324-0

Europium-doped calcium titanate nanophosphors were synthesized by the polymeric precursor method (PPM) at different temperatures. X-ray absorption near edge structure (XANES) spectroscopy reveals that the introduction of Eu3+ ions into the CaTiO3 network induces to significant changes in the local order disorder relationship around both [TiO6] and [CaO12] complex clusters. The X-ray diffraction (XRD) and FT-Raman reveals that the presence of the Eu3+ ions favors the structural organization at long and short ranges, which produces a faster crystallization of the CT orthorhombic phase. The increase of the annealed temperature and the Eu3+ concentration for CT:Eu3+ powders induces to a decrease in the CT:Eu3+ nanoparticle sizes. Crown Copyright (C) 2014 Published by Elsevier B.V. All rights reserved.

Formato

141-150

Identificador

http://dx.doi.org/10.1016/j.matchemphys.2014.01.051

Materials Chemistry And Physics. Lausanne: Elsevier Science Sa, v. 145, n. 1-2, p. 141-150, 2014.

0254-0584

http://hdl.handle.net/11449/111428

10.1016/j.matchemphys.2014.01.051

WOS:000334083200020

Idioma(s)

eng

Publicador

Elsevier B.V.

Relação

Materials Chemistry and Physics

Direitos

closedAccess

Palavras-Chave #Ceramics #Luminescence #Nanostructures #Optical properties
Tipo

info:eu-repo/semantics/article