Why silver deposition is so fast: Solving the enigma of metal deposition
| Contribuinte(s) |
Universidade Estadual Paulista (UNESP) |
|---|---|
| Data(s) |
27/05/2014
27/05/2014
22/07/2013
|
| Resumo |
A perfect match: Silver deposition is one of the fastest electrochemical reactions, even though the Ag+ ion loses more than 5 eV solvation energy in the process. This phenomenon, an example of the enigma of metal deposition, was investigated by a combination of MD simulations, DFT, and specially developed theory. At the surface, the Ag+ ion experiences a strong interaction with the sp band of silver, which catalyzes the reaction. Copyright © 2013 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim. |
| Formato |
7883-7885 |
| Identificador |
http://dx.doi.org/10.1002/anie.201301998 Angewandte Chemie - International Edition, v. 52, n. 30, p. 7883-7885, 2013. 1433-7851 1521-3773 http://hdl.handle.net/11449/76014 10.1002/anie.201301998 WOS:000321896800057 2-s2.0-84880359340 |
| Idioma(s) |
eng |
| Relação |
Angewandte Chemie - International Edition |
| Direitos |
closedAccess |
| Palavras-Chave | #corrosion #metal deposition #theoretical electrochemistry #Electrochemical reactions #MD simulation #Metal deposition #Perfect matches #Silver deposition #Solvation energy #Strong interaction #Catalysis #Chemistry #Corrosion #Deposition |
| Tipo |
info:eu-repo/semantics/article |
