Dba-free palladium intermediates of the Heck-Matsuda reaction
| Contribuinte(s) |
Universidade Estadual Paulista (UNESP) |
|---|---|
| Data(s) |
27/05/2014
27/05/2014
28/05/2013
|
| Resumo |
The dba-free Heck-Matsuda reaction was investigated via direct ESI-MS(/MS) monitoring. Palladium species involved in the reduction of Pd(ii) during a Wacker type reaction and several dba-free arylpalladium transient complexes were detected and characterized. Based on these findings, a more comprehensible catalytic cycle for this pivotal reaction is suggested. © 2013 The Royal Society of Chemistry. |
| Formato |
3277-3281 |
| Identificador |
http://dx.doi.org/10.1039/c3ob40142a Organic and Biomolecular Chemistry, v. 11, n. 20, p. 3277-3281, 2013. 1477-0520 http://hdl.handle.net/11449/75444 10.1039/c3ob40142a WOS:000318306400002 2-s2.0-84877257398 |
| Idioma(s) |
eng |
| Relação |
Organic and Biomolecular Chemistry |
| Direitos |
closedAccess |
| Palavras-Chave | #Catalytic cycles #Heck-matsuda reactions #Palladium intermediates #Palladium species #Transient complexes #Wacker-type reactions #Chemistry #Positive ions #Reaction intermediates |
| Tipo |
info:eu-repo/semantics/article |
