Sulfur-containing palladacycles as catalyst precursors for the heck reaction
| Contribuinte(s) |
Universidade Estadual Paulista (UNESP) |
|---|---|
| Data(s) |
27/05/2014
27/05/2014
04/05/2000
|
| Resumo |
(formula presented) The air, water, and highly thermally stable sulfur-containing palladacycles, mainly derived from the ortho-palladation of benzylic thioethers, are exceptional catalyst precursors for the Heck reaction. The reaction can be performed with aryl iodides, bromides, and chlorides, with acrylic esters and styrene, leading to turnover numbers up to 1 850 000. |
| Formato |
1287-1290 |
| Identificador |
http://dx.doi.org/10.1021/ol0057277 Organic Letters, v. 2, n. 9, p. 1287-1290, 2000. 1523-7060 http://hdl.handle.net/11449/66156 10.1021/ol0057277 2-s2.0-0001703882 |
| Idioma(s) |
eng |
| Relação |
Organic Letters |
| Direitos |
closedAccess |
| Tipo |
info:eu-repo/semantics/article |
