Synthesis and characterization of the mer-[RuCl3(NO)(dppb)] isomer. X-ray structures of fac-[RuCl3(NO)(dppm)], cis-[RuCl2(dppm)2] and mer-[RuCl3(NO)(dppb)] [dppm=1,2-Bis(diphenylphosphino)methane and dppb=1,4-Bis(diphenylphosphino)butane]
| Contribuinte(s) |
Universidade Estadual Paulista (UNESP) |
|---|---|
| Data(s) |
27/05/2014
27/05/2014
11/06/1999
|
| Resumo |
The fac-[RuCl3(NO)(dppm)] (1) and cis-[RuCl2(dppm)2] (2) complexes were obtained with co-crystallization in the solid state from the reaction of RuCl3(NO) with the diphosphine in dichloromethane. mer-[RuCl3(NO)(dppb)] (3) was obtained from [RuCl3(dppb)(H2O)] by bubbling NO for 30 min in the same solvent. The crystal and molecular structures of these three compounds have been determined from X-ray studies. © Elsevier Science Ltd. |
| Formato |
2079-2083 |
| Identificador |
http://dx.doi.org/10.1016/S0277-5387(99)00084-4 Polyhedron, v. 18, n. 15, p. 2079-2083, 1999. 0277-5387 http://hdl.handle.net/11449/65794 10.1016/S0277-5387(99)00084-4 WOS:000081794600011 2-s2.0-0000130862 |
| Idioma(s) |
eng |
| Relação |
Polyhedron |
| Direitos |
closedAccess |
| Palavras-Chave | #Complexes, Biphosphines #Isomerism #Nitrosyl #Ruthenium #X-ray structure |
| Tipo |
info:eu-repo/semantics/article |
