4-Dimethylaminocinnamylidenepyruvic acid: Synthesis, characterization and complexation with trivalent lanthanides, yttrium(III), scandium(III), thorium(IV) and uranium(VI) in aqueous solution


Autoria(s): Pereira, N. C S; Melios, C. B.; Marques, R. N.; Siqueira, O. S.; De Moraes, M.; Molina, M.; Ionashiro, Massao
Contribuinte(s)

Universidade Estadual Paulista (UNESP)

Data(s)

27/05/2014

27/05/2014

15/03/1997

Resumo

4-Dimethylaminocinnamylidenepyruvic acid (H-DMCP)and its sodium salt (Na-DMCP) have been synthesized and characterized. The protonation constant of DMCP as well as the stability constants of its binary 1:1 complexes with trivalent lanthanides (except Pm), Yttrium(III), Scandium(III), Thorium(IV) and Uranium(VI) were determined in an aqueous medium at 25°C and ionic strength 0.500 M. The mode of coordination of this ligand is discussed.

Formato

94-98

Identificador

http://dx.doi.org/10.1016/S0925-8388(96)02743-0

Journal of Alloys and Compounds, v. 249, n. 1-2, p. 94-98, 1997.

0925-8388

http://hdl.handle.net/11449/65075

10.1016/S0925-8388(96)02743-0

WOS:A1997XC09200018

2-s2.0-0041596944

Idioma(s)

eng

Relação

Journal of Alloys and Compounds

Direitos

closedAccess

Palavras-Chave #Cinnamylidenepyruvates #Metal-ion complexes #Protonation
Tipo

info:eu-repo/semantics/article