Phochemical behavior of trans-[Ru(NH3)4P(OEt)3L]2+ complex ions (L = P(OEt)3, CO, H2O)
| Contribuinte(s) |
Universidade Estadual Paulista (UNESP) |
|---|---|
| Data(s) |
27/05/2014
27/05/2014
01/12/1992
|
| Resumo |
trans-[Ru(NH3)4P(OEt)3H2O] 2+, trans-[Ru(NH3)4(P(OEt)3)]2+, and trans-[Ru(NH3)4P(OEt)3CO]2+ were photolyzed with light of 313 nm on the lowest energy ligand field excited state. Photoaquation of the thermally substitution inert ammonia is observed for all three complexes with φ ≅ 0.30 mol/einstein. trans-[Ru(NH3)4(P(OEt)3)2] 2+ undergoes P(OEt)3 photoaquation with φ ≅ 0.12 mol/einstein, while trans-[Ru(NH3)4P(OEt)3CO]2+ displays CO photoaquation with φ = 0.07 mol/einstein. The results suggest that the electronic configuration of the lowest energy excited state of these complexes have contributions from E and A2 states. Furthermore, in trans-[Ru(NH3)4P(OEt)3CO]2+ the photoaquation of CO is explained by depopulation of a bonding dπ orbital and population of a σ* orbital. © 1992 American Chemical Society. |
| Formato |
516-519 |
| Identificador |
http://dx.doi.org/10.1021/ic00029a033 Inorganic Chemistry, v. 31, n. 3, p. 516-519, 1992. 0020-1669 http://hdl.handle.net/11449/64299 10.1021/ic00029a033 2-s2.0-33751391332 |
| Idioma(s) |
eng |
| Relação |
Inorganic Chemistry |
| Direitos |
closedAccess |
| Tipo |
info:eu-repo/semantics/article |
