The role of oxygen vacancy in the photoluminescence property at room temperature of the CaTiO3
Contribuinte(s) |
Universidade Estadual Paulista (UNESP) |
---|---|
Data(s) |
20/05/2014
20/05/2014
15/08/2009
|
Resumo |
Fundação de Amparo à Pesquisa do Estado de São Paulo (FAPESP) Conselho Nacional de Desenvolvimento Científico e Tecnológico (CNPq) Coordenação de Aperfeiçoamento de Pessoal de Nível Superior (CAPES) Processo FAPESP: 98/14324-0 In this paper, electron paramagnetic resonance, photoluminescence (PL) emission, and quantum mechanical calculations were used to observe and understand the structural order-disorder of CaTiO3, paying special attention to the role of oxygen vacancy. The PL phenomenon at room temperature of CaTiO3 is directly influenced by the presence of oxygen vacancies that yield structural order-disorder. These oxygen vacancies bonded at Ti and/or Ca induce new electronic states inside the band gap. Ordered and disordered CaTiO3 was obtained by the polymeric precursor method. (C) 2009 American Institute of Physics. [DOI: 10.1063/1.3190524] |
Formato |
7 |
Identificador |
http://dx.doi.org/10.1063/1.3190524 Journal of Applied Physics. Melville: Amer Inst Physics, v. 106, n. 4, p. 7, 2009. 0021-8979 http://hdl.handle.net/11449/42378 10.1063/1.3190524 WOS:000270083800041 WOS000270083800041.pdf |
Idioma(s) |
eng |
Publicador |
American Institute of Physics (AIP) |
Relação |
Journal of Applied Physics |
Direitos |
closedAccess |
Tipo |
info:eu-repo/semantics/article |