The role of oxygen vacancy in the photoluminescence property at room temperature of the CaTiO3


Autoria(s): Milanez, Juliana; de Figueiredo, Alberthmeiry T.; de Lazaro, Sergio; Longo, Valeria M.; Erlo, Rafael; Mastelaro, Valmor R.; Franco, Roberto W. A.; Longo, Elson; Varela, José Arana
Contribuinte(s)

Universidade Estadual Paulista (UNESP)

Data(s)

20/05/2014

20/05/2014

15/08/2009

Resumo

Fundação de Amparo à Pesquisa do Estado de São Paulo (FAPESP)

Conselho Nacional de Desenvolvimento Científico e Tecnológico (CNPq)

Coordenação de Aperfeiçoamento de Pessoal de Nível Superior (CAPES)

Processo FAPESP: 98/14324-0

In this paper, electron paramagnetic resonance, photoluminescence (PL) emission, and quantum mechanical calculations were used to observe and understand the structural order-disorder of CaTiO3, paying special attention to the role of oxygen vacancy. The PL phenomenon at room temperature of CaTiO3 is directly influenced by the presence of oxygen vacancies that yield structural order-disorder. These oxygen vacancies bonded at Ti and/or Ca induce new electronic states inside the band gap. Ordered and disordered CaTiO3 was obtained by the polymeric precursor method. (C) 2009 American Institute of Physics. [DOI: 10.1063/1.3190524]

Formato

7

Identificador

http://dx.doi.org/10.1063/1.3190524

Journal of Applied Physics. Melville: Amer Inst Physics, v. 106, n. 4, p. 7, 2009.

0021-8979

http://hdl.handle.net/11449/42378

10.1063/1.3190524

WOS:000270083800041

WOS000270083800041.pdf

Idioma(s)

eng

Publicador

American Institute of Physics (AIP)

Relação

Journal of Applied Physics

Direitos

closedAccess

Tipo

info:eu-repo/semantics/article