Bulk and high-energy ball-milled Gd5Si2Ge2: Comparative study of magnetic and magnetocaloric properties


Autoria(s): do Couto, Giselle Giovanna; Svitlyk, Volodymyr; Jafelicci, Miguel; Mozharivskyj, Yurij
Contribuinte(s)

Universidade Estadual Paulista (UNESP)

Data(s)

20/05/2014

20/05/2014

01/01/2011

Resumo

High-energy ball milling was employed to produce small particles of Gd5Si2Ge2. Magnetic and magnetocaloric properties of the ball-milled and bulk Gd5Si2Ge2 samples were investigated through the magnetization measurements. When compared to the bulk material, a significant decrease in saturation magnetization and magnetocaloric effect (-Delta S-max = 4 vs. 20 J/kgK for Delta H = 0-5 T) is observed even after the relatively short ball milling time of 4 h which produced particles with an average size of ca. 0.5 mu m. The ball-milled samples appear to loose a first-order structural transition, present in bulk Gd5Si2Ge2, and display a superparamagnetic behaviour below the corresponding Curie temperatures. (C) 2010 Elsevier Masson SAS. All rights reserved.

Formato

209-215

Identificador

http://dx.doi.org/10.1016/j.solidstatesciences.2010.11.016

Solid State Sciences. Amsterdam: Elsevier B.V., v. 13, n. 1, p. 209-215, 2011.

1293-2558

http://hdl.handle.net/11449/41905

10.1016/j.solidstatesciences.2010.11.016

WOS:000287286000035

Idioma(s)

eng

Publicador

Elsevier B.V.

Relação

Solid State Sciences

Direitos

closedAccess

Palavras-Chave #Magnetic properties #Magnetocaloric properties #Ball milling #Structural transition
Tipo

info:eu-repo/semantics/article