Synthesis, characterization and thermal behaviour of solid-state compounds of light trivalent lanthanide succinates
Contribuinte(s) |
Universidade Estadual Paulista (UNESP) |
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Data(s) |
20/05/2014
20/05/2014
30/03/2010
|
Resumo |
Fundação de Amparo à Pesquisa do Estado de São Paulo (FAPESP) Conselho Nacional de Desenvolvimento Científico e Tecnológico (CNPq) Coordenação de Aperfeiçoamento de Pessoal de Nível Superior (CAPES) Characterization, thermal stability and thermal decomposition of light trivalent lanthanide succinates, Ln(2)(C(4)H(4)O(4))(3)center dot nH(2)O (Ln = La to Gd, except Pm) were investigated employing simultaneous thermogravimetry and differential thermal analysis (TG-DTA), differential scanning calorimetry (DSC), infrared spectroscopy, TG-FTIR system, elemental analysis and complexometry. The dehydration of the lanthanum and cerium compounds occurs in a single step, while for the praseodymium to gadolinium compounds the dehydration occurs in two consecutive steps. The thermal decomposition of the anhydrous compounds occurs in consecutive and/or overlapping steps, except for the cerium compound, with formation of the respective oxides, CeO(2), Pr(6)O(11) and Ln(2)O(3) (Ln = La, Nd to Gd), as final residue. The results also provided information concerning the denticity of the ligand and thermal behaviour of these compounds. (C) 2010 Elsevier BM. All rights reserved. |
Formato |
50-54 |
Identificador |
http://dx.doi.org/10.1016/j.tca.2010.01.001 Thermochimica Acta. Amsterdam: Elsevier B.V., v. 501, n. 1-2, p. 50-54, 2010. 0040-6031 http://hdl.handle.net/11449/41699 10.1016/j.tca.2010.01.001 WOS:000276136400009 |
Idioma(s) |
eng |
Publicador |
Elsevier B.V. |
Relação |
Thermochimica Acta |
Direitos |
closedAccess |
Palavras-Chave | #Light trivalent lanthanides #Succinate #Thermal behaviour |
Tipo |
info:eu-repo/semantics/article |