Chemical and spectroscopic studies of a new palladium(II) complex with N-acetyl-L-cysteine
| Contribuinte(s) |
Universidade Estadual Paulista (UNESP) |
|---|---|
| Data(s) |
20/05/2014
20/05/2014
01/01/2008
|
| Resumo |
Fundação de Amparo à Pesquisa do Estado de São Paulo (FAPESP) Processo FAPESP: 07/56317-1 Processo FAPESP: 06/55367-2 Processo FAPESP: 04/11106-5 Chemical and spectroscopic studies of a new palladium(II) N-acetyl-L-cysteine complex are described. Elemental analyses for the solid complex are consistent with the formula [Pd(C(5)H(8)NO(3)S)(2)] H(2)O or [Pd(NAC)(2)] H(2)O. Solid-state (13)C nuclear magnetic resonance (NMR), UV-Visible (UV-Vis) and infrared (IR) spectroscopic analyses are consistent with coordination of the ligand to palladium(II) through the nitrogen and sulfur atoms in a square-planar geometry. Thermogravimetric and differential thermal analyses confirmed the composition; final residue was identified as metallic palladium. |
| Formato |
3666-3673 |
| Identificador |
http://dx.doi.org/10.1080/00958970802108809 Journal of Coordination Chemistry. Abingdon: Taylor & Francis Ltd, v. 61, n. 22, p. 3666-3673, 2008. 0095-8972 http://hdl.handle.net/11449/41496 10.1080/00958970802108809 WOS:000260213000015 |
| Idioma(s) |
eng |
| Publicador |
Taylor & Francis Ltd |
| Relação |
Journal of Coordination Chemistry |
| Direitos |
closedAccess |
| Palavras-Chave | #N-acetyl-L-cysteine #Palladium(II) #(13)C NMR #Infrared spectroscopy #UV-Vis #Thermal analysis |
| Tipo |
info:eu-repo/semantics/article |
