REDUCTION OF THE AMIDO-BONDED (2-PICOLINAMIDO)PENTAAMMINERUTHENIUM(III) FOLLOWED BY FORMATION OF CIS-(2-PICOLINAMIDE)TETRAAMMINERUTHENIUM(II)
| Contribuinte(s) |
Universidade Estadual Paulista (UNESP) |
|---|---|
| Data(s) |
20/05/2014
20/05/2014
12/10/1994
|
| Resumo |
[(NH3)(5)Ru-III(2-NCpy)], obtained from electrochemical oxidation of the Ru(II) complex, undergoes hydrolysis to the amido-bonded [Ru-III(NHC(O)-2-py)]. The electrochemical reduction of this latter complex to Ru(II) is followed by an aquation reaction to form [R(II)(NH3)(5)(OH2)] and free picolinamide and a chelation reaction to form cis-[R(II)-(NH3)(4)(2-pica)] with the displacement of one cis ammonia. |
| Formato |
4619-4620 |
| Identificador |
Inorganic Chemistry. Washington: Amer Chemical Soc, v. 33, n. 21, p. 4619-4620, 1994. 0020-1669 http://hdl.handle.net/11449/38953 WOS:A1994PM68500007 |
| Idioma(s) |
eng |
| Publicador |
Amer Chemical Soc |
| Relação |
Inorganic Chemistry |
| Direitos |
closedAccess |
| Tipo |
info:eu-repo/semantics/article |
