SYNTHESIS AND CRYSTAL-STRUCTURE OF THE NOVEL CYCLOPALLADATED COMPLEX DI(MU,N-S-ETA(2)-QUINOLINE-2-THIOLATE)-BIS[(N,N-DIMETHYLBENZYLAMINE-C(2),N) PALLADIUM(II)]
Contribuinte(s) |
Universidade Estadual Paulista (UNESP) |
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Data(s) |
20/05/2014
20/05/2014
01/09/1993
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Resumo |
The compound di(mu,N-Seta2-2-quinoline-2-thiolate)-bis[(N,N-dimethylbenzylamine-C2,N)palladium(II)] was synthesized and studied by IR, NMR and X-ray diffraction: monoclinic, a = 20.138(3), b = 10.831(1), c = 14.973(2) angstrom, beta = 98.04(1)-degrees, Z = 4, space group P2(1)/c, R = 0.032. The compound is dimeric with the two [Pd(N,N-dimethylbenzylamine)]moieties being connected by the two vicinal bridging eta2-N,S-quinoline-2-thiolate anions in a square-planar coordination geometry for the palladium atoms. |
Formato |
495-497 |
Identificador |
Gazzetta Chimica Italiana. Rome: Soc Chimica Italiana, v. 123, n. 9, p. 495-497, 1993. 0016-5603 http://hdl.handle.net/11449/38925 WOS:A1993MG16800005 |
Idioma(s) |
eng |
Publicador |
Soc Chimica Italiana |
Relação |
Gazzetta Chimica Italiana |
Direitos |
closedAccess |
Tipo |
info:eu-repo/semantics/article |