Nanoscopic photoluminescence memory as a fingerprint of complexity in self-assembled alkyl/siloxane hybrids


Autoria(s): Carlos, Luis D.; Bermudez, Veronica de Zea; Amaral, Vitor S.; Nunes, Silvia C.; Silva, Nuno J. O.; Ferreira, Rute A. Sa; Rocha, Joao; Santilli, Celso Valentim; Ostrovskii, Denis
Contribuinte(s)

Universidade Estadual Paulista (UNESP)

Data(s)

20/05/2014

20/05/2014

05/02/2007

Resumo

A thermally activated photoluminescence memory effect, induced by a reversible order-disorder phase transition of the alkyl chains, is reported for highly organized bilayer alkyl/siloxane hybrids (see figure; left at room temperature, right at 120 degrees C). The emission energy is sensitive to the annihilation/formation of the hydrogen-bonded amide-amide array displaying a unique nanoscopic sensitivity (ca. 150 nm).

Formato

341-+

Identificador

http://dx.doi.org/10.1002/adma.200601435

Advanced Materials. Weinheim: Wiley-v C H Verlag Gmbh, v. 19, n. 3, p. 341-+, 2007.

0935-9648

http://hdl.handle.net/11449/38514

10.1002/adma.200601435

WOS:000244217800002

Idioma(s)

eng

Publicador

Wiley-Blackwell

Relação

Advanced Materials

Direitos

closedAccess

Tipo

info:eu-repo/semantics/article