Nonadiabatic calculations of the oscillator strengths for the helium atom in the hyperspherical adiabatic approach


Autoria(s): Masili, M.; De Groote, J. J.; Hornos, J. E.
Contribuinte(s)

Universidade Estadual Paulista (UNESP)

Data(s)

20/05/2014

20/05/2014

28/07/2000

Resumo

Energies and wavefunctions are calculated for the bound states of the helium atom in the hyperspherical adiabatic approach by the full inclusion of nonadiabatic couplings. We show that the use of appropriate asymptotic radial boundary conditions not only allows the efficient calculation of energies accurate up to a few ppm for the ground state but also gives increasingly precise results for high-lying excited states with a unique set of equations. The accuracy of the wavefunctions is demonstrated by the calculation of oscillator strengths in the length form for transitions between stares ii S-1(e) and (n + 1) P-1(0) up to n = 29, in agreement with variational calculations.

Formato

2641-2652

Identificador

http://dx.doi.org/10.1088/0953-4075/33/14/303

Journal of Physics B-atomic Molecular and Optical Physics. Bristol: Iop Publishing Ltd, v. 33, n. 14, p. 2641-2652, 2000.

0953-4075

http://hdl.handle.net/11449/38420

10.1088/0953-4075/33/14/303

WOS:000088752900004

Idioma(s)

eng

Publicador

Iop Publishing Ltd

Relação

Journal of Physics B: Atomic, Molecular and Optical Physics

Direitos

closedAccess

Tipo

info:eu-repo/semantics/article