Pyrazolyl coordination polymers of cadmium(II)
| Contribuinte(s) |
Universidade Estadual Paulista (UNESP) |
|---|---|
| Data(s) |
20/05/2014
20/05/2014
01/02/2006
|
| Resumo |
The coordination polymers [Cd(mu-Cl)(2)(HPz)(2)](n) (1) and [Cd(mu-1,3-SCN)(2)(HPz)(2)](n) (2) (HPz = pyrazole) have been prepared and characterized by elemental analysis, infrared spectroscopy, and single crystal X-ray diffraction. Both complexes exhibited chain structures made by linear arrays of Cd(II) bridged by chloro (1) or inversely related 1,3-SCN groups (2) and the pyrazole ligands at the apical. sites. Intermolecular hydrogen bonds and another non-covalent interactions are responsible for the self-assembly of linear chains into 2D networks. (c) 2005 Elsevier B.V. All rights reserved. |
| Formato |
235-238 |
| Identificador |
http://dx.doi.org/10.1016/j.inoche.2005.11.015 Inorganic Chemistry Communications. Amsterdam: Elsevier B.V., v. 9, n. 2, p. 235-238, 2006. 1387-7003 http://hdl.handle.net/11449/38305 10.1016/j.inoche.2005.11.015 WOS:000235269100028 |
| Idioma(s) |
eng |
| Publicador |
Elsevier B.V. |
| Relação |
Inorganic Chemistry Communications |
| Direitos |
closedAccess |
| Palavras-Chave | #coordination polymers #pyrazole #cadmium(II) #thiocyanate #non-covalent interactions #self-assembly |
| Tipo |
info:eu-repo/semantics/article |
