Synthesis, characterization and thermal behavior of complexes of Cu(II), Zn(II) and Cd(II) with S,S '-methylenebis(cysteine)


Autoria(s): Cavicchioli, M.; Corbi, P. P.; Melnikov, P.; Massabni, Antonio Carlos
Contribuinte(s)

Universidade Estadual Paulista (UNESP)

Data(s)

20/05/2014

20/05/2014

01/08/2002

Resumo

Synthesis and characterization, including data on thermal decomposition, are reported for the complexes of S,S'-methylenebis(cysteine) (djenkolic acid) with copper(II), zinc(II) and cadmium(II): CuC(7)H(12)N(2)O(4)S(2) [I]; ZnC(7)H(12)N(2)O(4)S(2) [II] and CdC(7)H(12)N(2)O(4)S(2) [III] X-ray diffraction showed that the compounds are isostructural and belong to a monoclinic system. According to IR spectra, COO, NH(2) groups and bridging sulfur atoms are the main coordination sites.

Formato

951-959

Identificador

http://dx.doi.org/10.1080/0095897022000002277

Journal of Coordination Chemistry. Abingdon: Taylor & Francis Ltd, v. 55, n. 8, p. 951-959, 2002.

0095-8972

http://hdl.handle.net/11449/37996

10.1080/0095897022000002277

WOS:000177699800010

Idioma(s)

eng

Publicador

Taylor & Francis Ltd

Relação

Journal of Coordination Chemistry

Direitos

closedAccess

Palavras-Chave #S,S '-methylenebis(cysteine) #djenkolic acid #transition metals #complexes
Tipo

info:eu-repo/semantics/article