Synthesis and structural characterization of dichlorobis (1-phenyl-3-methylpyrazole) palladium(II) and diazidobis (1-phenyl-3-methylpyrazole) palladiium(II)
Contribuinte(s) |
Universidade Estadual Paulista (UNESP) |
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Data(s) |
20/05/2014
20/05/2014
01/01/2001
|
Resumo |
Mononuclear pyrazolyl Pd(II) complexes of the type [PdX2(phmPz)(2)] (X = Cl-, N-3(-)) have been prepared. The 1-phenyl-3-methylpyrazole displaces acetonitrile from [PdCl2(CH3CN)(2)] to form [PdCl2(PhMPz)(2)] (phmPz = 1-phenyl-3-methylpyrazole) (1). [Pd(N-3)(2)(PhmPz)(2)] (2) could be obtained by metathesis from [PdCl2(CH3CN)(2)] or by substitution of the chloride in (1) by the azide ion. Both complexes were characterized by elemental analysis, infrared spectroscopy, H-1 and C-13 NMR and by single crystal X-ray diffraction. The coordination geometry around Pd(II) in these complexes is nearly square-planar, with the ligands in a trans configuration. |
Formato |
129-141 |
Identificador |
http://dx.doi.org/10.1080/00958970108027149 Journal of Coordination Chemistry. Philadelphia: Gordon Breach Publishing, Taylor & Francis Group, v. 54, n. 2, p. 129-141, 2001. 0095-8972 http://hdl.handle.net/11449/36889 10.1080/00958970108027149 WOS:000170693300004 |
Idioma(s) |
eng |
Publicador |
Gordon Breach Publishing, Taylor & Francis Group |
Relação |
Journal of Coordination Chemistry |
Direitos |
closedAccess |
Palavras-Chave | #pyrazole #palladium(II) #azide #infrared spectroscopy #NMR spectroscopy #X-ray diffraction |
Tipo |
info:eu-repo/semantics/article |