A 2D coordination polymer with brick-wall network topology based on the [Cu(NCS)(2)(pn)] monomer
| Contribuinte(s) |
Universidade Estadual Paulista (UNESP) |
|---|---|
| Data(s) |
20/05/2014
20/05/2014
01/07/2007
|
| Resumo |
The new complex [Cu(NCS)(2)(pn)] (1) (pn = 1,3-propanediamine) has been synthesized and characterized by elemental analysis, infrared and electronic spectroscopy. Single crystal X-ray diffraction studies revealed that complex 1 is made up of neutral [Cu(NCS)(2)(pn)] units which are connected by mu-1,3,3-thiocyanato groups to yield a 2D metal-organic framework with a brick-wall network topology. Intermolecular hydrogen bonds of the type NH...SCN and NH...NCS are also responsible for the stabilization of the crystal structure. (c) 2007 Elsevier B.V. All rights reserved. |
| Formato |
815-820 |
| Identificador |
http://dx.doi.org/10.1016/j.inoche.2007.04.005 Inorganic Chemistry Communications. Amsterdam: Elsevier B.V., v. 10, n. 7, p. 815-820, 2007. 1387-7003 http://hdl.handle.net/11449/35270 10.1016/j.inoche.2007.04.005 WOS:000247795000020 |
| Idioma(s) |
eng |
| Publicador |
Elsevier B.V. |
| Relação |
Inorganic Chemistry Communications |
| Direitos |
closedAccess |
| Palavras-Chave | #supramolecular chemistry #self-assembly #copper(II) #coordination polymer #hydrogen bonding |
| Tipo |
info:eu-repo/semantics/article |
