Microstructural evolution during sintering of CoO doped SnO2 ceramics


Autoria(s): Varela, José Arana; Cerri, J. A.; Leite, E. R.; Longo, Elson; Shamsuzzoha, M.; Bradt, R. C.
Contribuinte(s)

Universidade Estadual Paulista (UNESP)

Data(s)

20/05/2014

20/05/2014

01/01/1999

Resumo

Addition of 0.5 mol% of CoO into SnO2 promotes densification of this oxide to 99% of the theoretical density during sintering. TEM in this system reveals that after sintering at 1210 degrees C a secondary phase of Co2SnO4 is precipitated at the SnO2 grain boundaries during cooling. This phase is formed by diffusion of Co ions from the bulk to the grain boundary during sintering leaving needle-like defects at the grain bulk. The high resolution TEM micrograph of this system sintered at 1210 degrees C and 1400 degrees C showed an amorphous grain boundary region low in cobalt, indicating that the Co2SnO4 phase is precipitated from this region. (C) 1999 Elsevier B.V. Limited and Techna S.r.l. All rights reserved.

Formato

253-256

Identificador

http://dx.doi.org/10.1016/S0272-8842(98)00032-7

Ceramics International. Oxford: Elsevier B.V., v. 25, n. 3, p. 253-256, 1999.

0272-8842

http://hdl.handle.net/11449/32890

10.1016/S0272-8842(98)00032-7

WOS:000079365800008

Idioma(s)

eng

Publicador

Elsevier B.V.

Relação

Ceramics International

Direitos

closedAccess

Tipo

info:eu-repo/semantics/article