Self-assembly of metallosupramolecules directed by (N-H)(2)center dot center dot center dot SCN-M (M = Co, Ni), C-H center dot center dot center dot pi and pi-pi synthons
| Contribuinte(s) |
Universidade Estadual Paulista (UNESP) |
|---|---|
| Data(s) |
20/05/2014
20/05/2014
06/02/2006
|
| Resumo |
This work deals with the synthesis, spectroscopic and structural investigation of pyrazolyl complexes of the type trans-[M(NCS)(2)(HPz)(4)] {M=Co (1), Ni (2); HPz=pyrazole}. Single crystal X-ray studies on 1 and 2 reveal the formation of similar supramolecular arrangements derived from self-assembly of monomers linked together through intermolecular N-H center dot center dot center dot SCN hydrogen bonds, C-H center dot center dot center dot pi interactions and pi-pi stacking. (c) 2005 Elsevier B.V. All rights reserved. |
| Formato |
161-167 |
| Identificador |
http://dx.doi.org/10.1016/j.molstruc.2005.08.031 Journal of Molecular Structure. Amsterdam: Elsevier B.V., v. 783, n. 1-3, p. 161-167, 2006. 0022-2860 http://hdl.handle.net/11449/31675 10.1016/j.molstruc.2005.08.031 WOS:000235589000019 |
| Idioma(s) |
eng |
| Publicador |
Elsevier B.V. |
| Relação |
Journal of Molecular Structure |
| Direitos |
closedAccess |
| Palavras-Chave | #Co(II) and Ni(II) pyrazolyl complexes #thiocyanate #self-assembly #hydrogen bonding #supramolecular synthon |
| Tipo |
info:eu-repo/semantics/article |
