Thermal behavior of copper(II) pseudohalide complexes containing bidentate amines
Contribuinte(s) |
Universidade Estadual Paulista (UNESP) |
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Data(s) |
20/05/2014
20/05/2014
01/08/2002
|
Resumo |
Pseudohalide complexes of copper(II) with aliphatic bidentate amines, [Cu(N-3)(2)(N,N-diEten)](2) 1, [Cu(NCO)(2)(N,N-diEten)](2) 2, [Cu(NCO)(2)(N,N-diMeen)](2) 3, [Cu(N-3)(NCS)(N,N'-diMeen)](2) 4 and [Cu(N-3)(NCO)(N,N-diMeen)](2) 5 (N,N-diEten=N,N-diethylethylenediamine; N,N-diMeen=N,N- dimethyl-ethylenediamine and N,N'-diMeen = N,N'-dimethylethylenediamine), were prepared, characterized and their thermal behavior was investigated by TG curves. According to thermal analysis and X-ray diffraction patterns all compounds decomposed giving copper(II) oxide as final product. The mechanisms of decomposition were proposed and an order of thermal stability was established. |
Formato |
455-464 |
Identificador |
http://dx.doi.org/10.1023/A:1019947420249 Journal of Thermal Analysis and Calorimetry. Dordrecht: Kluwer Academic Publ, v. 69, n. 2, p. 455-464, 2002. 1418-2874 http://hdl.handle.net/11449/31330 10.1023/A:1019947420249 WOS:000177723200007 |
Idioma(s) |
eng |
Publicador |
Kluwer Academic Publ |
Relação |
Journal of Thermal Analysis and Calorimetry |
Direitos |
closedAccess |
Palavras-Chave | #bidentate amines #copper #infrared spectroscopy #pseudohalide #synthesis #thermal analysis |
Tipo |
info:eu-repo/semantics/article |