Electrochemical behavior of metallic chromium in chloride media


Autoria(s): Silva, G. C.; Vilchenski, M. C.; Sumodjo, PTA; Benedetti, Assis Vicente; Shifler, D. A.; Natishan, P. M.; Tsuru, T.; Ito, S.
Contribuinte(s)

Universidade Estadual Paulista (UNESP)

Data(s)

20/05/2014

20/05/2014

01/01/2000

Resumo

The electrochemical behavior of metallic chromium in aqueous solutions containing chloride ions at different pH was studied by means of open-circuit potential vs. time measurements, cyclic voltammetry and electrochemical impedance spectroscopy. The composition of the surface oxides was analyzed by XPS. For solutions with pH<3 the formation of a passive layer occurs via a dissolution/precipitation process while for pH>3 the mechanism changes. XPS analysis revealed that Cr2O3 basically constitutes the passive layer.

Formato

183-+

Identificador

http://www.thieme-connect.com/ejournals/abstract/10.1055/s-2006-949987

Corrosion and Corrosion Control In Saltwater Environments. Pennington: Electrochemical Society Inc., v. 99, n. 26, p. 183-+, 2000.

http://hdl.handle.net/11449/31178

WOS:000086691900019

Idioma(s)

eng

Publicador

Electrochemical Society Inc

Relação

Corrosion and Corrosion Control In Saltwater Environments

Direitos

closedAccess

Tipo

info:eu-repo/semantics/conferencePaper