Synthesis, characterization, and investigation of the thermal behavior of Cu(II) pyrazolyl complexes


Autoria(s): da Silva, Patricia B.; Terra, Paulo H.; Frem, Regina Célia Galvão; Netto, Adelino Vieira de Godoy; Mauro, Antonio Eduardo
Contribuinte(s)

Universidade Estadual Paulista (UNESP)

Data(s)

20/05/2014

20/05/2014

01/11/2011

Resumo

This work reports the synthesis, characterization, and thermal behavior of three complexes of copper (II): [CuCl(2)(HPz)(4)] (1), [CuCl(2)(HdmPz)(4)] (2), and [CuCl(2)(HIPz)(4)] (3) (HPz = pyrazole; HdmPz = 3,5-dimethylpyrazole; HIPz = 4-iodopyrazole). The compounds were characterized by elemental analysis, infrared spectroscopy, and UV-Vis measurements. The thermal study of the compounds showed that the ligands are eliminated in 2-4 stages, yielding CuO as final residue.

Formato

495-499

Identificador

http://dx.doi.org/10.1007/s10973-011-1296-0

Journal of Thermal Analysis and Calorimetry. Dordrecht: Springer, v. 106, n. 2, p. 495-499, 2011.

1388-6150

http://hdl.handle.net/11449/26078

10.1007/s10973-011-1296-0

WOS:000296065100030

Idioma(s)

eng

Publicador

Springer

Relação

Journal of Thermal Analysis and Calorimetry

Direitos

closedAccess

Palavras-Chave #Cu (II) complexes #Pyrazolyl ligands #Thermal analysis
Tipo

info:eu-repo/semantics/article