Aporphine and bisaporphine alkaloids from Aristolochia lagesiana var. intermedia


Autoria(s): Ferreira, Marcia L. R.; de Pascoli, Inara C.; Nascimento, Isabele Rodrigues; Zukerman-Schpector, Julio; Lopes, Lucia Maria Xavier
Contribuinte(s)

Universidade Estadual Paulista (UNESP)

Data(s)

20/05/2014

20/05/2014

01/03/2010

Resumo

Fundação de Amparo à Pesquisa do Estado de São Paulo (FAPESP)

Conselho Nacional de Desenvolvimento Científico e Tecnológico (CNPq)

Corydines, isocorydines, and analogous aporphine alkaloids were isolated from the leaves of Aristolochia lagesiana var intermedia, together with three bisaporphine salts (lagesianines B-D) Their structures were determined by chemical derivatizations and spectroscopic analyses Lagesianines B and C are the first examples of N-CH(2)-N' and C-2-O-C-1' linked dimeric aporphine alkaloids, respectively, while the monomeric units of lagesianine D. which has a carbon skeleton, are linked through C-7-C-5' via ail ethane-1,2-diol group (C-7-CHOHCHOH-C-5') (C) 2009 Elsevier Ltd. All rights reserved

Formato

469-478

Identificador

http://dx.doi.org/10.1016/j.phytochem.2009.11.010

Phytochemistry. Oxford: Pergamon-Elsevier B.V. Ltd, v. 71, n. 4, p. 469-478, 2010.

0031-9422

http://hdl.handle.net/11449/26063

10.1016/j.phytochem.2009.11.010

WOS:000275697900014

Idioma(s)

eng

Publicador

Pergamon-Elsevier B.V. Ltd

Relação

Phytochemistry

Direitos

closedAccess

Palavras-Chave #Aristolochia lagesiana var. intermedia #Aristolochiaceae #Alkaloids #Aporphine #Bisaporphine #Alkaloid dimer #Lagesianines #Corydine #Isocorydine #Corydine #N alpha-oxide
Tipo

info:eu-repo/semantics/article