Synthesis, characterization, and thermal behavior of palladium(II) coordination compounds containing isonicotinamide
| Contribuinte(s) |
Universidade Estadual Paulista (UNESP) |
|---|---|
| Data(s) |
20/05/2014
20/05/2014
01/11/2011
|
| Resumo |
Palladium(II) coordination compounds of general formula trans-[PdX(2)(isn)(2)], X = Cl(-) (1), N(3) (-) (2), SCN(-) (3), NCO(-) (4), isn = isonicotinamide; were synthesized and characterized in solid state by elemental analysis, infrared spectroscopy, and simultaneous TG-DTA. TG experiments reveal that the compounds 1-4 undergo thermal decomposition in three or four stages, yielding Pd(0) as final residue, according to calculus and identification by X-ray powder diffraction. |
| Formato |
375-378 |
| Identificador |
http://dx.doi.org/10.1007/s10973-010-1216-8 Journal of Thermal Analysis and Calorimetry. Dordrecht: Springer, v. 106, n. 2, p. 375-378, 2011. 1388-6150 http://hdl.handle.net/11449/26047 10.1007/s10973-010-1216-8 WOS:000296065100011 |
| Idioma(s) |
eng |
| Publicador |
Springer |
| Relação |
Journal of Thermal Analysis and Calorimetry |
| Direitos |
closedAccess |
| Palavras-Chave | #Palladium(II) #Isonicotinamide #TG-DTA #IR spectroscopy |
| Tipo |
info:eu-repo/semantics/article |
