Estudo da oxidação dos sulfetos sintéticos molibdenita (MoS2) e covelita (CuS) por Acidithiobacillus ferrooxidans via respirometria celular


Autoria(s): Francisco Junior, Wilmo E.; Bevilaqua, Denise; Garcia Júnior, Oswaldo[UNESP]
Contribuinte(s)

Universidade Estadual Paulista (UNESP)

Data(s)

20/05/2014

20/05/2014

01/01/2009

Resumo

Conselho Nacional de Desenvolvimento Científico e Tecnológico (CNPq)

This paper analyses the oxidation of covellite and molybdenite by Acidithiobacillus ferrooxidans strain LR using respirometric experiments. The results showed that both sulfides were oxidized by A. ferrooxidans, however, the covellite oxidation was much higher than molybdenite. Regarding the kinetic oxidation, the findings revealed that just molybdenite oxidation followed the classical Michaelis-Menten kinetic. It is probably associated with the pathway which these sulfides react to chemistry-bacterial attack, what is influenced by its electronic structures. Besides, experiments conducted in the presence of Fe3+ did not indicate alterations in molybdenite oxidation. Thus, ferric ions seem not to be essential to the sulfide oxidations.

Formato

1477-1481

Identificador

http://dx.doi.org/10.1590/S0100-40422009000600022

Química Nova. Sociedade Brasileira de Química, v. 32, n. 6, p. 1477-1481, 2009.

0100-4042

http://hdl.handle.net/11449/25355

10.1590/S0100-40422009000600022

S0100-40422009000600022

WOS:000270128800022

S0100-40422009000600022.pdf

Idioma(s)

por

Publicador

Sociedade Brasileira de Química

Relação

Química Nova

Direitos

openAccess

Palavras-Chave #sulfide oxidation #A. ferrooxidans #respirometric experiments
Tipo

info:eu-repo/semantics/article