Intense violet-blue photoluminescence in BaZrO3 powders: A theoretical and experimental investigation of structural order-disorder
| Contribuinte(s) |
Universidade Estadual Paulista (UNESP) |
|---|---|
| Data(s) |
30/09/2013
20/05/2014
30/09/2013
20/05/2014
15/07/2008
|
| Resumo |
Intense violet-blue photoluminescence (PL) emission at room temperature was verified in BaZrO3 (BZO) powders with structural order-disorder. Ab-initio calculations, ultraviolet-visible absorption spectroscopy and PL were performed. Theoretical results showed that the local disorder in the network-formed Zr clusters present an important role in the formation of hole-electron pair. The experimental data and theoretical results are in agreement, indicating that the PL emission in BZO powders can be related to the structural order-disorder degree in the lattice. (C) 2008 Elsevier B.V. All rights reserved. |
| Formato |
3715-3720 |
| Identificador |
http://dx.doi.org/10.1016/j.optcom.2008.03.069 Optics Communications. Amsterdam: Elsevier B.V., v. 281, n. 14, p. 3715-3720, 2008. 0030-4018 http://hdl.handle.net/11449/24995 10.1016/j.optcom.2008.03.069 WOS:000257047700018 |
| Idioma(s) |
eng |
| Publicador |
Elsevier B.V. |
| Relação |
Optics Communications |
| Direitos |
closedAccess |
| Palavras-Chave | #BaZrO3 #photoluminescence #structural order-disorder #optical absorption behavior and ab-initio calculations |
| Tipo |
info:eu-repo/semantics/article |
