Development of a simple and versatile ultrafiltration system for the fractionation of aquatic humic substances


Autoria(s): Pantano, Glaucia; Tadini, Amanda M.; Bisinoti, Marcia Cristina; Moreira, Altair Benedito; Santos, Ademir dos; Oliveira, Luciana Camargo de; Martin, Cibely S.
Contribuinte(s)

Universidade Estadual Paulista (UNESP)

Data(s)

20/05/2014

20/05/2014

01/02/2012

Resumo

Fundação de Amparo à Pesquisa do Estado de São Paulo (FAPESP)

Processo FAPESP: 07/50461-3

Processo FAPESP: 05/51242-8

A new fractionation system using membrane ultrafiltration was developed and applied to aqueous extracts of humic substances (HSs). Four polyethersulfone membranes of molecular weight cut offs of 10, 30, 50 and 100 kDa were used. The system was quite efficient in fractionating HSs with different molecular sizes. HS fractions were characterized by Fourier transform infrared spectroscopy and ultraviolet/visible spectrophotometry to obtain E-2/E-3 ratios, which describe the aromaticity of the fractions. The E-2/E-3 ratios were in agreement with those obtained using current commercial systems, and FTIR spectra of all fractions presented characteristic bands of the HSs. Therefore, it can be concluded that this system is a simple, versatile and low cost alternative to the current systems on the market. (C) 2011 Elsevier Ltd. All rights reserved.

Formato

156-161

Identificador

http://dx.doi.org/10.1016/j.orggeochem.2011.10.002

Organic Geochemistry. Oxford: Pergamon-Elsevier B.V. Ltd, v. 43, p. 156-161, 2012.

0146-6380

http://hdl.handle.net/11449/22250

10.1016/j.orggeochem.2011.10.002

WOS:000299815000015

Idioma(s)

eng

Publicador

Pergamon-Elsevier B.V. Ltd

Relação

Organic Geochemistry

Direitos

closedAccess

Tipo

info:eu-repo/semantics/article