Systematic analysis of the Fourier transform spectrum of (CH3OH)-C-13 between 400 and 950 cm(-1)


Autoria(s): Moraes, João Carlos Silos; Moruzzi, G.; Strumia, F.; Winnewisser, B. P.
Contribuinte(s)

Universidade Estadual Paulista (UNESP)

Data(s)

20/05/2014

20/05/2014

01/11/2005

Resumo

We have investigated a high-resolution Fourier transform (FT) absorption spectrum of the (CH3OH)-C-13 isotopomer of methanol from 400 to 950 cm(-1) with the Ritz program. We present the assignments of 7160 transitions, 3021 of which belong to Asymmetry, and 4139 to E-symmetry. These transitions occur between states labeled by K quantum numbers up to 14, and by torsional quantum numbers n up to 4. The Ritz program evaluated the energies of the 4684 involved levels with an accuracy of the order of 10(-4) cm(-1). All of the assigned lines correspond to transitions involving torsionally excited levels within the ground small-amplitude vibrational state. (c) 2005 Elsevier B.V. All rights reserved.

Formato

25-33

Identificador

http://dx.doi.org/10.1016/j.jms.2005.08.002

Journal of Molecular Spectroscopy. San Diego: Academic Press Inc. Elsevier B.V., v. 234, n. 1, p. 25-33, 2005.

0022-2852

http://hdl.handle.net/11449/9960

10.1016/j.jms.2005.08.002

WOS:000233537500003

Idioma(s)

eng

Publicador

Elsevier B.V.

Relação

Journal of Molecular Spectroscopy

Direitos

closedAccess

Palavras-Chave #Fourier transform spectra #(CH3OH)-C-13 assignment #far-infrared spectra #methanol #torsional excitation
Tipo

info:eu-repo/semantics/article