Systematic analysis of the Fourier transform spectrum of (CH3OH)-C-13 between 400 and 950 cm(-1)
Contribuinte(s) |
Universidade Estadual Paulista (UNESP) |
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Data(s) |
20/05/2014
20/05/2014
01/11/2005
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Resumo |
We have investigated a high-resolution Fourier transform (FT) absorption spectrum of the (CH3OH)-C-13 isotopomer of methanol from 400 to 950 cm(-1) with the Ritz program. We present the assignments of 7160 transitions, 3021 of which belong to Asymmetry, and 4139 to E-symmetry. These transitions occur between states labeled by K quantum numbers up to 14, and by torsional quantum numbers n up to 4. The Ritz program evaluated the energies of the 4684 involved levels with an accuracy of the order of 10(-4) cm(-1). All of the assigned lines correspond to transitions involving torsionally excited levels within the ground small-amplitude vibrational state. (c) 2005 Elsevier B.V. All rights reserved. |
Formato |
25-33 |
Identificador |
http://dx.doi.org/10.1016/j.jms.2005.08.002 Journal of Molecular Spectroscopy. San Diego: Academic Press Inc. Elsevier B.V., v. 234, n. 1, p. 25-33, 2005. 0022-2852 http://hdl.handle.net/11449/9960 10.1016/j.jms.2005.08.002 WOS:000233537500003 |
Idioma(s) |
eng |
Publicador |
Elsevier B.V. |
Relação |
Journal of Molecular Spectroscopy |
Direitos |
closedAccess |
Palavras-Chave | #Fourier transform spectra #(CH3OH)-C-13 assignment #far-infrared spectra #methanol #torsional excitation |
Tipo |
info:eu-repo/semantics/article |