Mono- and dinuclear palladium(II) compounds containing N,S donor ligands - Synthesis, characterization and thermal behavior


Autoria(s): Moro, A. C.; Mauro, A. E.; Ananias, S. R.; Stevanato, A.; Legendre, A. O.
Contribuinte(s)

Universidade Estadual Paulista (UNESP)

Data(s)

20/05/2014

20/05/2014

01/03/2007

Resumo

Synthesis, spectroscopic characterization and thermal analysis of the compounds [Pd-2(dmba)(2)(mu-NCO)(mu-2-qnS)] (1), [Pd-2(dmba)(2)(mu-NCO)(mu-8-qnS)] (2), [Pd(2-qnS)(2)] (3) and [Pd(8-qn(S))2] (4) (dmba=N,N-dimethylbenzylamine; 2-qnS=2-quinolinethiolate; 8-qnS=8-quinolinethiolate) are described. The thermal decomposition of these compounds occurs in four consecutive steps and the final decomposition products were identified as Pd(0) by X-ray powder diffraction. The thermal stability order of the complexes is 4 > 3 > 1 > 2.

Formato

721-724

Identificador

http://dx.doi.org/10.1007/s10973-006-7770-4

Journal of Thermal Analysis and Calorimetry. Dordrecht: Springer, v. 87, n. 3, p. 721-724, 2007.

1388-6150

http://hdl.handle.net/11449/7573

10.1007/s10973-006-7770-4

WOS:000244823700021

Idioma(s)

eng

Publicador

Springer

Relação

Journal of Thermal Analysis and Calorimetry

Direitos

closedAccess

Palavras-Chave #chelates #cyclopalladated compounds #quinolinethiol #thermal analysis
Tipo

info:eu-repo/semantics/article