A route to obtain Gd2O3:Nd3+ with different particle size


Autoria(s): Ferrari, J. L.; Parreira, R. L. T.; Pires, A. M.; Lima, S. A. M.; Davolos, M. R.
Contribuinte(s)

Universidade Estadual Paulista (UNESP)

Data(s)

20/05/2014

20/05/2014

16/05/2011

Resumo

Fundação de Amparo à Pesquisa do Estado de São Paulo (FAPESP)

Conselho Nacional de Desenvolvimento Científico e Tecnológico (CNPq)

Processo FAPESP: 03/10195-1

This work reports the chemical etching effect of ethylenediaminetetraacetic acid (H(4)EDTA) on the particle size of Gd2O3:Nd3+ phosphor obtained from the thermal decomposition of Gd-2(OH)(2)(CO3)center dot nH(2)O:Nd3+. Thermogravimetric behavior of the precursor Gd-2(OH)(2)(CO3)center dot nH(2)O:Nd3+ (2 at%) is presented and discussed. Structural and spectroscopic investigation of the Gd2O3:Nd3+ powders revealed that this phosphor displays a band emission in the infrared region, which is an important feature for photonic applications. The treatment with different EDTA concentrations results in different Gd2O3:Nd3+ particle size. Through SEM analysis, we have demonstrated that the particle size of Gd2O3:Nd3+ decreases with increasing amount of EDTA. Hereby, we report a chemical etching method as a route to obtain particle size control which is an important requirement to improve phosphor properties and its applicability. (C) 2010 Elsevier B.V. All rights reserved.

Formato

40-44

Identificador

http://dx.doi.org/10.1016/j.matchemphys.2010.11.055

Materials Chemistry and Physics. Lausanne: Elsevier B.V. Sa, v. 127, n. 1-2, p. 40-44, 2011.

0254-0584

http://hdl.handle.net/11449/6896

10.1016/j.matchemphys.2010.11.055

WOS:000289322800008

Idioma(s)

eng

Publicador

Elsevier B.V. Sa

Relação

Materials Chemistry and Physics

Direitos

closedAccess

Palavras-Chave #Optical material #Etching #Inorganic compounds
Tipo

info:eu-repo/semantics/article