Competition between cluster fragmentation, C–C bond coupling and C–X bond activation in silver hexynyl cluster cations, [(C4H9CCAg)nAg]+. Size does matter!


Autoria(s): Wang, Farrah Qiuyun; Khairallah, George N.; Koutsantonis, George A.; Williams, Craig M.; Callahan, Damien L.; O’Hair, Richard A.J.
Data(s)

01/01/2009

Resumo

Silver hexynyl cluster cations, [(C4H9CCAg)nAg]+, exhibit a rich unimolecular chemistry that is dependant on the cluster size, n (1–5), cluster fragmentation (for all n > 1); C–C bond coupling (n = 3 & 4); C–H bond activation with comcomitant silver hydride formation (n = 1 & 4); C–C bond activation (n = 1 & 4).

Identificador

http://hdl.handle.net/10536/DRO/DU:30083164

Idioma(s)

eng

Publicador

Royal Society of Chemistry

Relação

http://dro.deakin.edu.au/eserv/DU:30083164/wang-competitionbetween-2009.pdf

http://www.dx.doi.org/10.1039/b904687a

Direitos

2009, Royal Society of Chemistry

Tipo

Journal Article