Oxygen transfer from an intramolecularly coordinated diaryltellurium oxide to acetonitrile. formation and combined AIM and ELI-D analysis of a novel diaryltellurium acetimidate
Data(s) |
15/07/2014
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Resumo |
The reaction of the intramolecularly coordinated diaryltellurium(IV) oxide (8-Me2NC10H6)2TeO with acetonitrile proceeds with oxygen transfer and gives rise to the formation of the novel zwitterionic diaryltelluronium(IV) acetimidate (8-Me2NC 10H6)2TeNC(O)CH3 (1) in 57% yield. Hydrolysis of 1 with hydrochloric acid affords acetamide and the previously known diarylhydroxytelluronium(IV) chloride [(8-Me2NC 10H6)2Te(OH)]Cl. © 2014 American Chemical Society. |
Identificador | |
Idioma(s) |
eng |
Publicador |
American Chemical Society |
Relação |
http://www.dx.doi.org/10.1021/ja505648x |
Direitos |
2014, American Chemical Society |
Tipo |
Journal Article |