[Al4(OH)2(OCH3)4(H2N-bdc)3]⋅x H2O: A 12-connected porous metal–organic framework with an unprecedented aluminum-containing brick
Data(s) |
29/06/2009
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Resumo |
A new stable aluminum aminoterephthalate system contains octameric building blocks that are connected by organic linkers to form a 12-connected net (see picture). The structure adopts a cubic centered packing motive in which octameric units replace individual atoms, thus forming distorted octahedral (red sphere) and tetrahedral cages (green spheres) with effective accessible diameters of 1 and 0.45 nm, respectively |
Identificador | |
Idioma(s) |
eng |
Publicador |
Wiley |
Relação |
http://dro.deakin.edu.au/eserv/DU:30064472/gunzelmann-connectedporous-2009.pdf http://dx.doi.org/10.1002/anie.200901409 |
Direitos |
2009, Wiley |
Palavras-Chave | #organic-inorganic hybrid composites #high-throughput methods #metal-organic frameworks #microporous materials #solvothermal synthesis |
Tipo |
Journal Article |