The synthesis of a dichloroalane complex and its reaction with an α-diimine
| Data(s) |
01/01/2008
|
|---|---|
| Resumo |
Reaction of an α-diimine, {MesN[double bond, length as m-dash]CH}2 (Mes = 2,4,6-trimethylphenyl), with the dichloroalane [AlCl2H(IMes)] (IMes = 1,3-bis(2,4,6-trimethylphenyl)imidazol-2-ylidene) affords an N-heterocyclic carbene (NHC) transfer complex [AlCl2{MesNC([double bond, length as m-dash]IMes)C(H)NMes}] rather than the expected hydroalumination product. |
| Identificador | |
| Idioma(s) |
eng |
| Publicador |
Royal Society of Chemistry |
| Relação |
http://dro.deakin.edu.au/eserv/DU:30063858/hilder-synthesisofdichloroalane-2008.pdf http://dx.doi.org/10.1039/B814839B |
| Direitos |
2008, Royal Society of Chemistry |
| Palavras-Chave | #dichloroalane complex |
| Tipo |
Journal Article |
