Immobilization of large, aliovalent cations in the small-pore zeolite K-natrolite by means of pressure
Data(s) |
14/05/2012
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Resumo |
High-pressure ion exchange of small-pore zeolite K-natrolite allows immobilization of nominally non-exchangeable aliovalent cations such as trivalent europium. A sample exchanged at 3.0(1) GPa and 250 °C contains about 4.7 Eu<sup>III</sup> ions per unit cell, which is equivalent to over 90 % of the K<sup>+</sup> cations being exchanged.<br /> |
Identificador | |
Idioma(s) |
eng |
Publicador |
Wiley - V C H Verlag GmbH & Co. KGaA |
Relação |
http://dro.deakin.edu.au/eserv/DU:30047733/liu-immobilizationof-2012.pdf http://dx.doi.org/10.1002/anie.201201045 |
Direitos |
2012, Wiley-VCH Verlag |
Palavras-Chave | #high-pressure chemistry #ion exchange #lanthanides #X-ray diffraction #zeolites |
Tipo |
Journal Article |