Depolymerization of aryltellurinic anhydrides with sodium hydroxide. Synthesis and structure of the hydrated sodium aryltellurinates [Na(H2O)4](RTeO2) (R = 4-MeOC6H4, 8-Me2NC10H6)
| Data(s) |
01/01/2012
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|---|---|
| Resumo |
Depolymerization of the aryltellurinic anhydrides [(RTe)<sub>2</sub>O<sub>3</sub>]<sub>n</sub> (9, R = 4-MeOC<sub>6</sub>H<sub>4</sub>; 6, R = 8-Me<sub>2</sub>NC<sub>10</sub>H<sub>6</sub>) with aqueous NaOH afforded the hydrated sodium aryltellurinates [Na(H<sub>2</sub>O)<sub>4</sub>](4-MeOC<sub>6</sub>H<sub>4</sub>TeO<sub>2</sub>) (10) and [Na(H<sub>2</sub>O)<sub>4</sub>](8-Me<sub>2</sub>NC<sub>10</sub>H<sub>6</sub>TeO<sub>2</sub>)·H<sub>2</sub>O (11·H<sub>2</sub>O) as highly crystalline materials. |
| Identificador | |
| Idioma(s) |
eng |
| Publicador |
American Chemical Society |
| Relação |
http://dro.deakin.edu.au/eserv/DU:30047046/duthie-depolymerizationofaryl-2012.pdf http://dx.doi.org/10.1021/om300130a |
| Direitos |
2012, American Chemical Society |
| Tipo |
Journal Article |
