Ionic conduction in doped succinonitrile
| Data(s) |
30/11/2004
|
|---|---|
| Resumo |
Doping of lithium salts into the plastic crystal phase of succinonitrile does significantly increase ionic conductivity. This paper investigates the effect of anion (TFSA, Tf and BF<sub>4</sub>) on the conductivity and diffusion of the mobile species using impedance spectroscopy and NMR. Room temperature conductivities up to 2.1×10<sup>−4</sup> S cm<sup>−1</sup> were obtained with 1 mol% lithium bis(trifluoromethanesulfonyl)amide in succinonitrile. Pulse field gradient NMR has shown that in all three systems investigated, both cation and anion are mobile in this lattice.<br /> |
| Identificador | |
| Idioma(s) |
eng |
| Publicador |
Elsevier |
| Relação |
http://dro.deakin.edu.au/eserv/DU:30030183/forsyth-ionicconduction-2004.pdf http://dx.doi.org/10.1016/j.ssi.2003.11.042 |
| Direitos |
2004, Elsevier B.V. |
| Palavras-Chave | #molecular plastic crystals #ionic conductivity #diffusion #solid electrolytes #lithium |
| Tipo |
Journal Article |
