Synthesis and characterisation of rare earth complexes supported by para-substituted Cinnamate Ligands
Data(s) |
01/01/2009
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Resumo |
The preparations and characterisations of a range of lanthanoid 4-(R)-substituted (4-Rcinn, R = OH, OMe, NO2, Cl), known to have good anticorrosion properties, are reported. The crystal structure of [Ce(4-OHcinn)3(MeOH)2(H2O)]·MeOH is a polymer, in which the cerium atoms are nonacoordinate, and adjacent cerium atoms are bridged by either two bridging bidentate or two bridging tridentate carboxylate ligands. Each cerium atom also has one monodentate 4-hydroxycinnamate ligand, one aqua ligand, and two methanol ligands.<br /> |
Identificador | |
Idioma(s) |
eng |
Publicador |
Wiley |
Relação |
http://dro.deakin.edu.au/eserv/DU:30030179/forsyth-synthesisandcharacterisation-2009.pdf http://dx.doi.org/10.1002/zaac.200801379 |
Direitos |
2009 Wiley-VCH Verlag GmbH & Co. KGaA |
Palavras-Chave | #lanthanides #cinnamates #x-ray diffraction #rare earth compounds |
Tipo |
Journal Article |