Crystal structure of a ceIII/feIII heterobimetallic complex
| Data(s) |
01/08/2003
|
|---|---|
| Resumo |
A central μ<sub>3</sub>—O moiety linking two Fe<sup>III</sup> and one Ce<sup>III</sup> sites supported by two distinct heterometallic carboxylate bridging modes features in self-assembled [CeFe<sub>2</sub>(bpy)<sub>2</sub>(μ<sub>3</sub>—O)(μ—L)<sub>2</sub>(μ—LH)<sub>2</sub>(LH)(H<sub>2</sub>O)<sub>2</sub>]·0.5(bpy)·7H<sub>2</sub>O (<b>1</b>) (LH<sub>2</sub> = glycolic acid), and the structure models potential bonding modes of the Rare Earth corrosion inhibitor Ce(glycolate)<sub>3</sub> to iron or iron oxide.<br /> |
| Identificador | |
| Idioma(s) |
eng |
| Publicador |
Wiley Interscience |
| Relação |
http://dro.deakin.edu.au/eserv/DU:30030100/forsyth-crystallstructure-2003.pdf http://dx.doi.org/10.1002/zaac.200300089 |
| Direitos |
2003, WILEY-VCH Verlag GmbH & Co. KGaA |
| Palavras-Chave | #cerium #glycolate #iron #oxide #corrosion |
| Tipo |
Journal Article |
