Heterometallic CeIII–FeIII–salicylate networks : models for corrosion mitigation of steel surfaces by the ′Green′ inhibitor, Ce(salicylate)3
| Data(s) |
01/01/2002
|
|---|---|
| Resumo |
The syntheses and structures of the novel Ce–Fe bimetallic complexes [{Fe(sal)<sub>2</sub>(bpy)}<sub>2</sub>Ce(NO<sub>3</sub>)(H<sub>2</sub>O)<sub>3</sub>]·EtOH and [{Fe(sal)<sub>2</sub>(bpy)}<sub>4</sub>Ce<sub>2</sub>(H<sub>2</sub>O)<sub>11</sub>][salH]<sub>2</sub>·EtOH·3H<sub>2</sub>O (salH<sub>2</sub> = salicylic acid) suggest Fe<sup>3+</sup>–sal<sup>2−</sup> units and Ce–OC(R)O–Fe bridging contribute to the formation of corrosion inhibitive layers on steel surfaces exposed to [Ce(salH)<sub>3</sub>(H<sub>2</sub>O)].<br /> |
| Identificador | |
| Idioma(s) |
eng |
| Publicador |
Royal Society of Chemistry |
| Relação |
http://dro.deakin.edu.au/eserv/DU:30030098/forsyth-heterometallic-2002.pdf http://dx.doi.org/10.1039/B207722A |
| Direitos |
2002, The Royal Society of Chemistry |
| Tipo |
Journal Article |
