Synthesis and polymerization studies of 3-(+) and (-) -menthyl carboxylate pyrroles
Data(s) |
01/11/2007
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Resumo |
The synthesis of 3-(−)- and 3-(+)-menthyl carboxylate pyrrole was achieved in four high yielding steps, including the triisopropylsilyl (TIPS) protection of the pyrrole nitrogen, bromination of the 3-position, lithium halogen exchange followed by reaction with menthyl chloroformate, and finally de-protection. Chemical polymerization of both the TIPS protected, and non-protected, menthyl carboxylate pyrroles was performed and the resulting polymers exhibited conductivity ranging from 0.6 to 2.3 S/cm. Polymerization of the 3-menthyl-<i>N</i>-TIPS pyrrole on the surface of wool was achieved by using solution and mist polymerization methods.<br /> |
Identificador | |
Idioma(s) |
eng |
Publicador |
Elsevier SA |
Relação |
http://dro.deakin.edu.au/eserv/DU:30007636/kaynak-synthesisandpolymerization-2007.pdf http://dx.doi.org/10.1016/j.synthmet.2007.09.003 |
Direitos |
2007, Elsevier B.V. |
Palavras-Chave | #conductive polymers #chiral polymers #wool #coloured polymers #chemical polymerization |
Tipo |
Journal Article |