Synthesis, molecular structure, and isomerisation in solution of (Me3SbS)2Me2SnCl2. Concomitant hypercoordination of tin and antimony
Data(s) |
01/01/2003
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Resumo |
The reaction of Me<sub>3</sub>SbCl<sub>2</sub> and (Me<sub>2</sub>SnS)<sub>3</sub> afforded the complex (Me<sub>3</sub>SbS)<sub>2</sub>Me<sub>2</sub>SnCl<sub>2</sub> in high yields, whose molecular structure features both hypercoordinated tin and antimony atoms. In solution, (Me<sub>3</sub>SbS)<sub>2</sub>Me<sub>2</sub>SnCl<sub>2</sub> undergoes a reversible dissociation and ligand interchange reaction to give Me<sub>3</sub>SbS, Me<sub>3</sub>SbCl<sub>2</sub> and (Me<sub>2</sub>SnS)<sub>3</sub>.<br /> |
Identificador | |
Idioma(s) |
eng |
Publicador |
Wiley Interscience |
Relação |
http://dro.deakin.edu.au/eserv/DU:30002060/duthie-synthesismolecular-2003.pdf http://dx.doi.org/10.1002/zaac.200300102 |
Direitos |
2003, WILEY-VCH Verlag |
Palavras-Chave | #tin #antimony #hypercoordination #crystal structures #NMR spectroscopy |
Tipo |
Journal Article |