Synthesis and molecular structure of [n-Bu2(F)SnOSn(F)t-Bu2]2 - an unsymmetrically substituted tetraorganodistannoxane

Autoria(s): Beckmann, Jens; Dakternieks, Dainis; Duthie, Andrew; Jurkschat, Klaus; Schurmann, Markus
Data(s)

01/01/2003
Resumo

The dimeric tetraorganodistannoxane [<i>n</i>-Bu<sub>2</sub>(F)SnOSn(F)<i>t</i>-Bu<sub>2</sub>]<sub>2</sub> (<b>1</b>) was prepared by the reaction of (<i>t</i>-Bu<sub>2</sub>SnO)<sub>3</sub> with <i>n</i>-Bu<sub>2</sub>SnF<sub>2</sub> and characterized in solution by multinuclear NMR spectroscopy and ESI MS spectrometry and in the solid state by <sup>119</sup>Sn MAS NMR spectroscopy and single crystal X-ray diffraction.<br />
Identificador

http://hdl.handle.net/10536/DRO/DU:30001972
Idioma(s)

eng
Publicador

Wiley Interscience
Relação

http://dro.deakin.edu.au/eserv/DU:30001972/duthie-synthesisand-2003.pdf

http://dx.doi.org/10.1002/zaac.200390023
Direitos

2003, WILEY-VCH Verlag
Palavras-Chave #tin #fluorine #tetraorganodistannoxane #NMR #crystal structure
Tipo

Journal Article
Acesso ao item digital